Prepare a shot of espresso and let it cool to room temperature.
Chill a martini glass in the freezer or by filling it with ice water.
In a cocktail shaker, add the chai-infused vodka, coffee liqueur, cooled espresso, and simple syrup.
Fill the shaker with ice cubes and shake vigorously for about 10-15 seconds.
Discard the ice from the chilled martini glass.
Use a strainer to pour the shaken mixture into the glass.
Garnish with a dash of chai spices and coffee beans.
Your Chai Espresso Martini is ready to be savored! Sip slowly and relish the delightful combination of chai spices and espresso.